Derivatisation of Saturated Hydrocarbons: A Facile One-step Formation of N-(1-Adamantyl)acetamide from Adamantane.
نویسندگان
چکیده
منابع مشابه
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.
Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially medium-sized rings, are limited. We describe the development of SnAP (Sn amino protocol) reagents for the transformation of aldehydes into seven-, eight- and nine-membered saturated N-heterocycles....
متن کاملFacile one-step photopatterning of polystyrene films
The development of nanoand micropatterned materials is a key component of advanced nanotechnology. We report herein, a photo-based method for patterning general-purpose polymer films. Patterned ultraviolet (UV) light irradiation of a thin polystyrene film under controlled temperature generates surface relief structures by mass transfer from shaded to irradiated areas. The resulting surface reli...
متن کاملA Facile One-Pot Synthesis of Functionalized N-Hydroxypyrrole Mediated by Vinyl-Triphenylphosphonium Salt
Protonation of the reactive intermediates generated in the raction between dalkyl acetylenedicarboxylates and triphenylphosphine by isonitrosoacetophenone leads to vinyltriphenylphosphonium salts, which undergo intramolecular Wittig reaction to produce dalkyl 4-phenyl-N-hydroxypyrrole-2,3-dicarboxylates in moderate yields.
متن کاملOne-pot and one-step novel N-methylation of 2,6-diaminopyridine
2,6-diaminopyridine is extensively used as a pharmaceutical intermediate and a hair dye coupler as oxidation formulations. It is soluble in protic solvents. Primary and secondary amines are N-methylated by various methods such as direct alkylation of amines with Hofmann mechanism, but in many of these methods due to overalkylations, we earn a mixture of amino products. Consequently, they aren't...
متن کاملEigenvalues of Saturated Hydrocarbons
A simplified Hückel-type molecular-orbital (MO) model for the valence electrons of saturated hydrocarbons is proposed and the consequent eigenvalue spectrum considered. A first foundational result is obtained, which every chemist “knows”, namely that: alkanes are stable, with half their (Hückeltype MO) eigenvalues positive and half negative.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1989
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.43-0399